Syntheses and crystal structures of neutral tetrairon complexes with the unique SCPPh2S ligand.
نویسندگان
چکیده
The novel reactions of cluster salts [(μ-RS)Fe(2)(CO)(6)(μ(4)-CS(2))Fe(2)(CO)(6)][Et(3)NH] with Ph(2)PCl, via the insertion of the PPh(2) group into an activated C-S bond, afford the unprecedented tetrairon complexes with the unique SCPPh(2)S ligand which is coordinated to (μ-RS)Fe(2)(CO)(6) and Fe(2)(CO)(6) units in a μ(4)-k(2)C:k(4)S,S' mode (R = Ph, CH(3)O(2)CCH(2)).
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ورودعنوان ژورنال:
- Chemical communications
دوره 49 22 شماره
صفحات -
تاریخ انتشار 2013